Physics

Equivalent circuit

Mechanics

Porosity

Internal resistance

Internal heating

Thermal resistance

Voltage

Composite material

Power (physics)

Electrical impedance

Tortuosity

Materials science

Thermal

Thermal diffusivity

Battery (electricity)

Quantum mechanics

Thermal conductivity

Thermodynamics

Batteries

This paper presents three equivalent thermal circuit models with multiple input parameters, namely, the state of health (SOH), state of charge (SOC), current and temperature. Typical physiochemical models include parameters such as porosity and tortuosity, which are not easily experimentally available; this model allows for model parameters such as the internal impedance to be easily estimated using more practical inputs. The paper models the internal impedance resistance of a LiFePO4 battery at five different ambient temperatures (5, 15, 25, 35, 45 °C), at three different discharge rates (1C, 2C, 3C) and at three different SOHs (90%, 83%, 65%). The internal impedance surface fit experimental measurements with a Pearson coefficient of 0.945. Three thermal models were then created that implemented the internal resistance model. The first two thermal models were 0D models that did not include the influence of the thermal conductivity of the battery. The first model assumed simple heating through internal resistance and convection energy loss, while the second also included the Bernardi Reversible heat term. The final third model was a 2D model that included all previous heat source terms as well as tab heating. The 2D model was solved using a simple Euler method and finite center difference. The R2 values for the 0D thermal models were 0.9964 and 0.9962 for the simple internal resistance and reversible heating models, respectively. The R2 value for the 2D thermal model was 0.996.

Thermal Modelling Utilizing Multiple Experimentally Measurable Parameters