Internal resistance

Thermoelectric generator

Physics

Contact resistance

Engineering

Electrical contacts

Fabrication

Thermal resistance

Pathology

Physical chemistry

Meteorology

Composite material

Power (physics)

Nanotechnology

Electrode

Chemistry

Thin film

Materials science

Thermal

Alternative medicine

Layer (electronics)

Chemical engineering

Optoelectronics

Battery (electricity)

Thermal stability

Quantum mechanics

Thermoelectric effect

Medicine

Flexible electronics

Bending

Electrical resistance and conductance

Thermodynamics

Advanced Energy Materials

High relative contact electrical resistance and poor flexibility in inorganic thin‐film thermoelectric devices significantly limit their practical applications. To overcome this challenge, a one‐step thermal diffusion method to fabricate assembly‐free inorganic thin‐film thermoelectric devices is developed, where the in situ grown electrode delivers an excellent leg‐electrode contact, leading to high output power and flexibility in the prepared p‐type Sb 2 Te 3 /n‐type Bi 2 Te 3 thin‐film device, which is composed of 8 pairs of p‐n junctions. Such a device shows a very low relative contact electrical resistance of 7.5% and a high power density of 1.42 mW cm –2 under a temperature difference of 60 K. Less than 10% change of the whole electrical resistance before and after bending test indicates the robust bending resistance and stability of the device. This study indicates that the novel assembly‐free one‐step thermal diffusion method can effectively enhance the leg‐electrode contact, the device thermoelectric performance, bending resistance, and stability, which can inspire the development of thin‐film thermoelectric devices.

Assembly‐Free Fabrication of High‐Performance Flexible Inorganic Thin‐Film Thermoelectric Device Prepared by a Thermal Diffusion