Total Synthesis of Resveratrone and iso ‐Resveratrone

Published on Jun 30, 2022in ChemistryOpen
· DOI :10.1002/open.202200098
Stefan Fritsch0 (University of Duisburg-Essen), Nazli Aldemir0 (University of Duisburg-Essen)+ 3 AuthorsChristoph Hirschhäuser11
Estimated H-index: 11
(University of Duisburg-Essen)
The first total synthesis of resveratrone and iso-resveratrone based on an epoxide olefination approach is described. The pivotal reaction proceeds by insertion of the lithiated epoxide into a boronic ester and subsequent syn-elimination. Resveratrone has been described to have remarkable photophysical properties, including two-photon absorption. Therefore, an azide derivative has been prepared to allow for use as a biological label.
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