Total Synthesis of Resveratrone and <i>iso</i>‐Resveratrone
Volume: 11, Issue: 7
Published: Jun 30, 2022
The first total synthesis of resveratrone and iso-resveratrone based on an epoxide olefination approach is described. The pivotal reaction proceeds by insertion of the lithiated epoxide into a boronic ester and subsequent syn-elimination. Resveratrone has been described to have remarkable photophysical properties, including two-photon absorption. Therefore, an azide derivative has been prepared to allow for use as a biological...