Cluster Compounds with Oxidised, Hexanuclear [Nb 6 Cl i 12 I a 6 ] n Anions ( n =2 or 3)

Volume: 11, Issue: 6
Published: Jun 1, 2022
Abstract
Four mixed-halide cluster salts with chloride-iodide-supported octahedral Nb6 metal atoms cores were prepared and investigated. The cluster anions have the formula [Nb6 Cli12 Ia6 ]n- with Cl occupying the inner ligand sites and I the outer one. They are one- or two-electron-oxidized (n=2 or 3) with respect to the starting material cluster. (Ph4 P)+ and (PPN)+ function as counter cations. The X-ray structures reveal a mixed occupation of the...
Paper Details
Title
Cluster Compounds with Oxidised, Hexanuclear [Nb 6 Cl i 12 I a 6 ] n Anions ( n =2 or 3)
Published Date
Jun 1, 2022
Volume
11
Issue
6
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