Quantum mechanics

Catalysis

Materials science

Superlattice

Transition metal

Biochemistry

Molecule

Semiconductor

Polariton

Physics

Exciton

van der Waals force

Condensed matter physics

Exciton-polaritons

Heterojunction

Chemistry

Optoelectronics

Nature Reviews Materials

Atomically thin transition metal dichalcogenides (TMDs) are 2D semiconductors with tightly bound excitons and correspondingly strong light–matter interactions. Owing to the weak van der Waals bonding between layers, TMDs can be isolated and stacked together to form synthetic heterostructures with emergent electronic and excitonic properties. In this Review, we focus on the emergent exciton physics in moiré superlattices and in TMD heterobilayers coupled to optical cavities, where exciton behaviour can be dramatically modified by the environment. In moiré superlattices, a small twist angle or lattice mismatch between the layers introduces a periodic variation in the interlayer alignment that leads to exciton localization, modified optical selection rules and strong correlations. In cavity–heterostructure systems, light–matter interaction is enhanced and exciton states can couple to the cavity to form exciton-polaritons, whose properties depend on the specific TMD layers involved and their alignment. Here, we discuss recent theoretical and experimental progress towards realizing exotic exciton states in TMD heterobilayers and comment on future scientific and technological directions. 2D semiconductor heterostructures host tightly bound exciton states that interact strongly with light. This Review discusses two approaches for realizing emergent excitonic physics in these systems: the introduction of a moiré superlattice and the formation of an optical cavity.

Emerging exciton physics in transition metal dichalcogenide heterobilayers