Estimation of the temperature dependence of the vaporization enthalpies of monofunctional aliphatic compounds

An approach for prediction of the temperature dependence of the vaporization enthalpies of monofunctional aliphatic compounds was developed and validated, based on 782 vaporization enthalpies of 303 monofunctional aliphatic compounds at the temperature range from 220 to 600 K. RMS (root-mean-square deviation between the predicted and experimental data) was 1.6 kJ•mol−1 and AD (average deviation) was 0.0 kJ•mol−1. Within the proposed approach,...