Unified one-electron Hamiltonian formalism of spin–orbit Jahn–Teller and pseudo-Jahn–Teller problems in axial symmetries

Spin-orbit coupling and vibronic coupling are both closely related to orbital degeneracy of electronic states. Both types of coupling play significant roles in determining properties of heavy element compounds and shall be treated on the same footing. In this work, we derive a unified one-electron Hamiltonian formalism for spin-orbit and vibronic interactions for systems in all axial symmetries. The one-electron formalism is usually adequate as...