Can you break the oxo-wall? A multiconfigurational perspective

The concept of the "oxo-wall" was conceived about 60 years ago by Harry B. Gray, and has been found to be related to the non-existence of high-valent M-oxo species in the +IV oxidation state in a tetragonal geometry beyond group 8 in the periodic table. Several efforts have been made in the past decades to test and find examples that violate this theory. Several claims of violation in the past were attributed to the difference in the...