Concise synthesis and applications of enantiopure spirobiphenoxasilin-diol and its related chiral ligands
Abstract
The development of chiral architectures for chiral ligand and catalyst discovery is essential for asymmetric catalysis. Herein, we report the concise synthesis of a Si-centered spirocyclic skeleton, spirobiphenoxasilin-diol (SPOSiOL), and its derived chiral ligands. Using the chemical resolution method, the optical SPOSiOL could be obtained in high yield on a gram scale. Preliminary studies indicated that this ligand scaffold has great potential...
Paper Details
Title
Concise synthesis and applications of enantiopure spirobiphenoxasilin-diol and its related chiral ligands
Published Date
Jan 1, 2021
Journal
Volume
57
Issue
98
Pages
13365 - 13368
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