Total Synthesis of Pulvomycin D
Volume: 28, Issue: 3
Published: Dec 7, 2021
Abstract
A synthetic route to the pulvomycin class of natural products is presented, which culminated in the first synthesis of a pulvomycin, pulvomycin D. Key elements of the strategy include a pivotal aldol reaction which led to bond formation between the C24-C40 and the C8-C23 fragment. The remaining C1-C7 fragment was attached by a Yamaguchi esterification completing the assembly of the 40 carbon atoms within the main skeleton. Ring closure to the...
Paper Details
Title
Total Synthesis of Pulvomycin D
Published Date
Dec 7, 2021
Volume
28
Issue
3
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