Self-Assembly of a Lantern-Like Zirconium Metal–Organic Cage Decorated with μ2-OH Functional Groups for Potential Al3+ Ion Detection
Abstract
A novel lantern-like zirconium metal–organic cage (Zr-OPBA) has been synthesized via coordination-driven self-assembly of flexible ditopic carboxylate ligand and zirconocene. Zr-OPBA featuring terminal spatially isolated μ2-OH has been fully characterized by single-crystal X-ray crystallography, high-resolution mass spectrometry, and 1H NMR. As a proof of concept, Zr-OPBA with high luminescence was used as a fluorescent probe to detect Al3+ ion...
Paper Details
Title
Self-Assembly of a Lantern-Like Zirconium Metal–Organic Cage Decorated with μ2-OH Functional Groups for Potential Al3+ Ion Detection
Published Date
Nov 17, 2021
Journal
Volume
21
Issue
12
Pages
6642 - 6647
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