Weakly hydrated anions bind to polymers but not monomers in aqueous solutions
Abstract
Weakly hydrated anions help to solubilize hydrophobic macromolecules in aqueous solutions, but small molecules comprising the same chemical constituents precipitate out when exposed to these ions. Here, this apparent contradiction is resolved by systematically investigating the interactions of NaSCN with polyethylene oxide oligomers and polymers of varying molecular weight. A combination of spectroscopic and computational results reveals that...
Paper Details
Title
Weakly hydrated anions bind to polymers but not monomers in aqueous solutions
Published Date
Nov 1, 2021
Journal
Volume
14
Issue
1
Pages
40 - 45
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