Electrochemical analysis in charge-transfer science: The devil in the details

It is easy to carry out electrochemical analysis. It is demanding, however, to do it right, as inherent challenges, emerging from details in the data collection and the result interpretation, frequently present themselves. In pertinence to electron-donor-acceptor interactions, herein, we focus on voltammetrically obtained electrochemical potentials and their immense utility for extracting important characteristics of molecular analytes....