Grafting copolymer brushes on polyhedral oligomeric silsesquioxanes silsesquioxane-decorated silica stationary phase for hydrophilic interaction liquid chromatography
Abstract
A strategy is proposed to develop a stationary phase for hydrophilic interaction liquid chromatography (HILIC) using the synergistic effect of polyhedral oligomeric silsesquioxane (POSS) and copolymer brushes. Octahedral octa-aminopropylsisesquioxane (8NH2-POSS) was first bound to silica gel, followed by bromination to form a cubic initiator. Then, using acrylamide (AM) and dihydroxypropyl methacrylate (DPMA) as mixed monomers, surface...
Paper Details
Title
Grafting copolymer brushes on polyhedral oligomeric silsesquioxanes silsesquioxane-decorated silica stationary phase for hydrophilic interaction liquid chromatography
Published Date
Dec 1, 2021
Journal
Volume
1659
Pages
462627 - 462627
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