N-Donor stabilized tin(ii) cations as efficient ROP catalysts for the synthesis of linear and star-shaped PLAsviathe activated monomer mechanism

α-Iminopyridine ligands L1 (2-(CHN(C6H2-2,4,6-Ph3))C5H4N), L2 (2-(CHN(C6H2-2,4,6-tBu3))C5H4N) and L3 (1,2-(C5H4N-2-CHN)2CH2CH2) differing by the steric demand of the substituent on the imine CHN group and by the number of donating nitrogen atoms were utilized to initiate a Lewis base mediated ionization of SnCl2 in an effort to prepare ionic tin(II) species [L1-3 → SnCl][SnCl3]. The reaction of L1 and L2 with SnCl2 led to the formation of...