Interdigitated Pt-Br chains with π-stacking: an approach toward Robin-Day class I mixed valency in MX-chain complexes
Abstract
The first interdigitated MX-type chain complex with infinite π-stacked arrays was synthesized. The synchronization between a Pt–Br⋯ chain and π-stacking periodicities led to the longest M–X–M distance (6.6978(15) A) and nil or negligible intervalence charge transfer, which is essential to realize the Robin–Day class I mixed valence state in MX...
Paper Details
Title
Interdigitated Pt-Br chains with π-stacking: an approach toward Robin-Day class I mixed valency in MX-chain complexes
Published Date
Oct 19, 2021
Journal
Volume
50
Issue
40
Pages
14125 - 14129
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