Surface‐Dependent Intermediate Adsorption Modulation on Iridium‐Modified Black Phosphorus Electrocatalysts for Efficient pH‐Universal Water Splitting

2D black phosphorus (BP) is one promising electrocatalyst toward hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) catalysis. The too strong adsorption of oxygen intermediates during OER, while the too weak adsorption of hydrogen intermediate during HER, however, greatly compromise its practical water splitting applications with overpotentials as high as 450 mV for OER and 420 mV for HER to achieve 10 mA cm −2 under alkaline...