Preliminary exploration on enzyme-promoted asymmetric biomimetic synthesis of resveratrol dimers
Abstract
The asymmetric biomimetic synthesis of resveratrol dimers was preliminarily explored using the enzyme-mediated oxidative coupling reactions of chiral resveratrol derivatives as the key step. The horseradish peroxidase-H2O2-promoted oxidations of 11,13-di-sec-butyl resveratrol ether and 3,5-dibromo-resveratrol di-sec-butyl ethers generated an 8-5-coupled intermediate and several 8-8-coupled dimeric mixtures, respectively. The acid-catalyzed...
Paper Details
Title
Preliminary exploration on enzyme-promoted asymmetric biomimetic synthesis of resveratrol dimers
Published Date
Sep 22, 2021
Journal
Volume
51
Issue
22
Pages
3449 - 3459
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