Bimetal Cooperatively Catalyzed Arylalkynylation of Alkynylsilanes
Abstract
An unprecedented Pd/Rh cooperatively catalyzed arylalkynylation of alkynylsilanes was developed to merge an alkynylidene moiety with benzosilacycle. These silaarenes possess a particular aggregation-induced emission behavior. Mechanistic investigations demonstrate that the relay trimetallic transmetalation plays a pivotal role in governing this...
Paper Details
Title
Bimetal Cooperatively Catalyzed Arylalkynylation of Alkynylsilanes
Published Date
Aug 16, 2021
Journal
Volume
23
Issue
17
Pages
6724 - 6728
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