Conformationally Switchable Silylone: Electron Redistribution Accompanied by Ligand Reorientation around a Monatomic Silicon

Complexes that could be switched between two electronic states by external stimuli have attracted much attention for their potential application in molecular devices. However, a realization of such a phenomenon with low-valent main-group element-centered complexes remains challenging. Herein, we report the synthesis of cyclic (alkyl)(amino)silylene (CAASi)-ligated monatomic silicon(0) complexes (silylones). The bis(CAASi)-ligated silylone adopts...