Coulombic effect on permeation of CO2 in metal-organic framework membranes
Abstract
Comparing the aperture size of a membrane to the kinetic diameters of gases to be separated has long been regarded as the rule of thumb for identifying potential membrane materials. This method based upon molecular sieving could however fail for CO 2 separations using metal-organic frameworks (MOFs). While the challenge may be attributed to the breathing effect or linker rotation for some highly flexible MOFs, the adsorbent-adsorbate Coulombic...
Paper Details
Title
Coulombic effect on permeation of CO2 in metal-organic framework membranes
Published Date
Dec 1, 2021
Journal
Volume
639
Pages
119742 - 119742
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