High Double Bond Content of Polyisoprene Synthesis via Cationic Polymerization Synergistically Catalyzed by Tf2NH-Ionic Liquids
Abstract
The highly selective cationic polymerization of isoprene has been a great challenge over the last 70 years. Here, a synergistic Tf2NH-ionic liquid (IL) catalytic system has been developed to address this issue under mild conditions. Tf2NH serves as a highly efficient catalyst for the cationic polymerization with 0.01 mol % loading, and its counteranion IL serves as a remarkable selectivity-controlled medium delivering low-molecular-weight (Mn <...
Paper Details
Title
High Double Bond Content of Polyisoprene Synthesis via Cationic Polymerization Synergistically Catalyzed by Tf2NH-Ionic Liquids
Published Date
Jun 29, 2021
Journal
Volume
54
Issue
13
Pages
6109 - 6116
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