Copper atoms inlaid in titanium zirconium oxide spherical shell confine free radicals for the robust Fenton-like treatment of complex biogas slurry

A novel Fenton-like system based on single-atom catalysts was developed for the treatment of biogas slurry under 90 °C conditions. First, a binary composite was synthesized in which porous TiZrO4 hollow spheres provided sites for embedding Cu atoms and confining generated free radicals to promote the efficiency of oxidation reactions. The TiZrO4/Cu catalyst mediated the simultaneous oxidation of approximately 69 % of the chemical oxygen demand...