Fabrication of Hierarchical Macroporous ZIF-8 Monoliths Using High Internal Phase Pickering Emulsion Templates

The shaping of metal–organic frameworks (MOFs), referring to the integration of small sub-millimeter MOF crystals into bulk samples of desired size and shape, is an important step in the practical use of this class of porous material in many applications. Herein, we demonstrate for the first time the fabrication of hierarchical 3D MOF monoliths in situ within an MOF particle-stabilized high internal phase emulsion (HIPE). In this approach, a...