Photogenerated Hole-Induced Chemical–Chemical Redox Cycling Strategy on a Direct Z-Scheme Bi₂S₃/Bi₂MoO₆ Heterostructure Photoelectrode: Toward an Ultrasensitive Photoelectrochemical Immunoassay

To achieve high sensitivity for biomolecule detection in photoelectrochemical (PEC) bioanalysis, the ideal photoelectrode and ingenious signaling mechanism play crucial roles. Herein, the feasibility of the photogenerated hole-induced chemical–chemical redox cycling amplification strategy on a Z-scheme heterostructure photoelectrode was validated, and the strategy toward enhanced multiple signal amplification for advanced PEC immunoassay...