Multicomponent Spiropolymerization of Diisocyanides, Diethyl Acetylenedicarboxylate, and Halogenated Quinones

Volume: 42, Issue: 12, Pages: 2100029 - 2100029
Published: May 14, 2021
Abstract
Multicomponent spiropolymerization (MCSP) provides an efficient synthetic tool for the construction of spiropolymers based on nonspiro monomers. In this study, a method of MCSP using diisocyanides 1, diethyl acetylenedicarboxylate 2, and halogenated quinones 3 is developed for the in situ construction of bis-spiropolymers with high molecular weights (Mw up to 29 200) and good yields (up to 87.7%) under mild reaction conditions. The structure of...
Paper Details
Title
Multicomponent Spiropolymerization of Diisocyanides, Diethyl Acetylenedicarboxylate, and Halogenated Quinones
Published Date
May 14, 2021
Volume
42
Issue
12
Pages
2100029 - 2100029
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