Constraints on isomers of dissolved organic matter in aquatic environments: Insights from ion mobility mass spectrometry

Elucidating the chemical structure of dissolved organic matter (DOM) is key to understanding this large yet enigmatic carbon pool. Over the last two decades much progress has been made in assigning exceptionally accurate molecular formulas of DOM owing to the application of ultrahigh resolution mass spectrometry, but little is known about the number of isomers in each molecular formula, a question essentially related to the total number of...