Enantioselective access to chiral aliphatic amines and alcohols via Ni-catalyzed hydroalkylations
Abstract
Chiral aliphatic amine and alcohol derivatives are ubiquitous in pharmaceuticals, pesticides, natural products and fine chemicals, yet difficult to access due to the challenge to differentiate between the spatially and electronically similar alkyl groups. Herein, we report a nickel-catalyzed enantioselective hydroalkylation of acyl enamines and enol esters with alkyl halides to afford enantioenriched α-branched aliphatic acyl amines and esters...
Paper Details
Title
Enantioselective access to chiral aliphatic amines and alcohols via Ni-catalyzed hydroalkylations
Published Date
May 13, 2021
Journal
Volume
12
Issue
1
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