Isoreticular chemistry within metal–organic frameworks for gas storage and separation

Precise control of the pore size and environment of metal–organic framework (MOF) is a necessary condition for achieving high performance of gas adsorption and separation. After nearly two decades of development, the synthesis of MOF materials has gradually evolved from exploration and trial to precise-design, including function-oriented microstructure design and optimization, pore size tailoring, and secondary building unit (SBU) modification....