Highly Efficient Non-Fused-Ring Electron Acceptors Enabled by the Conformational Lock and Structural Isomerization Effects

Two novel nonfused-ring electron acceptors (N-FREAs) namely DTP-out-F and DTP-in-F, containing 2,5-difluorophenylene central core flanked with DTP blocks and end-capped with IC-2F terminals were designed and synthesized. The C–H···F noncovalent interactions between F atom of 2,5-difluorophenylene and H-3 and H-6 from DTP moiety (for DTP-in-F and DTP-out-F, respectively) locked the molecular conformation within a planar geometry. Benefiting from...