Interweaving Visible‐Light and Iron Catalysis for Nitrene Formation and Transformation with Dioxazolones
Abstract
Herein, visible-light-driven iron-catalyzed nitrene transfer reactions with dioxazolones for intermolecular C(sp3)-N, N=S, and N=P bond formation are described. These reactions occur with exogenous-ligand-free process and feature satisfactory to excellent yields (up to 99 %), an ample substrate scope (109 examples) under mild reaction conditions. In contrast to intramolecular C−H amidations strategies, an intermolecular regioselective C−H...
Paper Details
Title
Interweaving Visible‐Light and Iron Catalysis for Nitrene Formation and Transformation with Dioxazolones
Published Date
May 10, 2021
Journal
Volume
60
Issue
30
Pages
16426 - 16435
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