Quadruply BN‐Fused Tetrathia[8]circulenes with Flexible Frameworks: Synthesis, Structures and Properties

Quadruply BN‐fused tetrathia[8]circulenes were synthesized through four‐fold electrophilic borylation. The single‐crystal X‐ray diffraction analysis revealed that the BN‐fused tetrathia[8]circulene with peripheral phenyl groups exhibits crystal polymorphism, in which the circulene core adopts both planar and saddle conformations in the solid state. The experimental and theoretical studies revealed that the weaker aromaticity of azaborine...