Evaporation thermodynamics of the tetraoctylphosphonium bis(trifluoromethansulfonyl)imide([P8888]NTf2) and tetraoctylphosphonium nonafluorobutane-1-sulfonate ([P8888]NFBS) ionic liquids

The evaporation/thermaldecompositionbehaviour of twoionicliquids with phosphoniumcation (PhosphoniumIonicLiquids, PhosphoniumILs,), namelytetraoctylphosphonium bis(trifluoromethansulfonyl)imide ([P8888]NTf2) and tetraoctylphosphonium perfluorobutylphosphonate ([P8888]NFBS) wasstudied by thermogravimetryand by the effusion-basedtechniques Knudsen Effusion Mass Spectrometry (KEMS) and Knudsen Effusioni Mass Loss (KEML). KEMS spectra show that no...