V═O Functionalized {Tm₂}–Organic Framework Designed by Postsynthesis Modification for Catalytic Chemical Fixation of CO₂ and Oxidation of Mustard Gas

In terms of recently documented references, the introduction of V═O units into porous MOF/COF frameworks can greatly improve their original performance and expand their application prospects due to a change in their electronegativity. In this work, by a cation-exchange strategy, a consummate combination of separate 4f [Tm2(CO2)8] SBUs and 3d [VIVO(H2O)2] units generated the functionalized porous metal–organic framework...