Metallophthalocyanines derived with phenyl sulfide by bridging triazole using click chemistry: Synthesis, Computational Study, Redox Chemistry and Catalytic Activity

Synthesis and characterization of new metallophthalocyanines (M = Zn, Co (II) and Ni (II)) carrying four new triazole units in peripheral positions was presented in this paper. First, 4-(prop-2-yn-1-yloxy)phthalonitrile, 3, was synthesized. Second, azidomethyl phenyl sulfide, 4, was added to this structure in order to obtain a triazole unit catalyzed by sodium ascorbate and CuSO4.5H2O in DMSO. Common spectroscopic methods such as FT-IR, 1H-NMR,...