Enantioselective C–H Alkenylation of Ferrocenes with Alkynes by Half-Sandwich Scandium Catalyst

Volume: 143, Issue: 6, Pages: 2470 - 2476
Published: Feb 2, 2021
Abstract
The enantioselective C–H alkenylation of ferrocenes with alkynes is, in principle, a straightforward and atom-efficient route for the construction of planar-chiral ferrocene scaffolds bearing alkene functionality but has remained scarcely explored to date. Here we report for the first time the highly enantioselective C–H alkenylation of quinoline- and pyridine-substituted ferrocenes with alkynes by a half-sandwich scandium catalyst. This...
Paper Details
Title
Enantioselective C–H Alkenylation of Ferrocenes with Alkynes by Half-Sandwich Scandium Catalyst
Published Date
Feb 2, 2021
Volume
143
Issue
6
Pages
2470 - 2476
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