SYNTHESIS OF 4-AMINO-1,2,4-TRIAZOLES AND1,3,4-OXADIAZOLES FROM PALMITIC AND OLEIC ACIDS AS LIGANDS OF PALLADIUM(II) COMPLEXES

Two 4-amino-1,2,4-triazoles-3-thiones and two 1,3,4-oxadiazoles-2-thiones derived from two long chain fatty acids saturated «palmitic acid» and unsaturated «oleic acid» are obtained in a common synthetic route. For the oleic acid derivatives, a hydrogenation of the carbon-carbon double bond by hydrazidation of the intermediate oleic hydrazide under atmospheric air is implemented. New palladium complexes, derived from these...