Nanomaterials

Nanotechnology

Nanocrystal

Organic chemistry

Metal-organic framework

Crystallization

Membrane

Porosity

Adsorption

Engineering

Composite material

Chemistry

Metallurgy

Materials science

Zeolitic imidazolate framework

Oxide

Graphene

Chemical engineering

Nanosheet

Biochemistry

Microporous material

Microstructure

Nature Nanotechnology

The robustness of carbon nanomaterials and their potential for ultrahigh permeability has drawn substantial interest for separation processes. However, graphene oxide membranes (GOms) have demonstrated limited viability due to instabilities in their microstructure that lead to failure under cross-flow conditions and applied hydraulic pressure. Here we present a highly stable and ultrapermeable zeolitic imidazolate framework-8 (ZIF-8)-nanocrystal-hybridized GOm that is prepared by ice templating and subsequent in situ crystallization of ZIF-8 at the nanosheet edges. The selective growth of ZIF-8 in the microporous defects enlarges the interlayer spacings while also imparting mechanical integrity to the laminate framework, thus producing a stable microstructure capable of maintaining a water permeability of 60 l m−2 h−1 bar−1 (30-fold higher than GOm) for 180 h. Furthermore, the mitigation of microporous defects via ZIF-8 growth increased the permselectivity of methyl blue molecules sixfold. Low-field nuclear magnetic resonance was employed to characterize the porous structure of our membranes and confirm the tailored growth of ZIF-8. Our technique for tuning the membrane microstructure opens opportunities for developing next-generation nanofiltration membranes. Highly stable and ultrapermeable membranes can be fabricated by the hybridization of zeolitic imidazolate framework-8 and graphene oxide.

Graphene oxide membranes with stable porous structure for ultrafast water transport