Decoupling Poly(3-alkylthiophenes)' Backbone and Side-Chain Conformation by Selective Deuteration and Neutron Scattering

Published on Dec 3, 2020in Macromolecules5.918
· DOI :10.1021/ACS.MACROMOL.0C02086
Zhiqiang Cao10
Estimated H-index: 10
(USM: University of Southern Mississippi),
Zhaofan Li1
Estimated H-index: 1
(NDSU: North Dakota State University)
+ 6 AuthorsXiaodan Gu29
Estimated H-index: 29
(USM: University of Southern Mississippi)
Although considerable progress has been made to optimize the optoelectronic properties of conjugated polymers (CPs), the rational design of CPs with tailored physical properties for end-use applica...
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Conjugated polymers are a promising candidate for large-area stretchable electronics because of their tunable electrical and mechanical properties, light weight, and low-cost solution processing. S...
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Doping of polymeric semiconductors is often limited by the miscibility issue between polymers and dopants. Although significant efforts have been devoted to enhancing the miscibility via chemical modification, the electrical conductivities of n-doped polymeric semiconductors are usually below 10 S cm -1 . Here, we report a different approach to overcome the miscibility issue by modulating the solution-state aggregates of conjugated polymers. We found that the solution-state aggregates of conjuga...
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