Synthesis and Reduction of a Cyclic (Alkyl)(amino)bromoborane to Generate a Thermally Labile Cyclic (Alkyl)(amino)boryl Anion
Abstract
A cyclic (alkyl)(amino)bromoborane (CAABBr) was synthesized by a reaction of the corresponding hydroborane with bromine in the presence of triethylamine. Reduction of the resulting CAABBr with Li powder and 4,4′-di-tert-butylbiphenyl (DBB) generated a thermally labile cyclic (alkyl)(amino)boryllithium (CAABLi) which was characterized by NMR spectroscopy. Quenching of the mixture reduced by Li/DBB with methanol-d1 or MeOTf at low temperature gave...
Paper Details
Title
Synthesis and Reduction of a Cyclic (Alkyl)(amino)bromoborane to Generate a Thermally Labile Cyclic (Alkyl)(amino)boryl Anion
Published Date
Feb 5, 2021
Journal
Volume
50
Issue
2
Pages
293 - 296
Citation AnalysisPro
You’ll need to upgrade your plan to Pro
Looking to understand the true influence of a researcher’s work across journals & affiliations?
- Scinapse’s Top 10 Citation Journals & Affiliations graph reveals the quality and authenticity of citations received by a paper.
- Discover whether citations have been inflated due to self-citations, or if citations include institutional bias.
Notes
History