Physics

Engineering

Oxygen evolution

Physical chemistry

Composite material

Catalysis

Power (physics)

Nanotechnology

Electrode

Organic chemistry

Inorganic chemistry

Chemistry

Metallurgy

Materials science

Bifunctional

Electrocatalyst

Chemical engineering

Optoelectronics

Cobalt

Electrochemistry

Oxygen

Battery (electricity)

Doping

Quantum mechanics

Porosity

Advanced Science

Limited by the sluggish four-electron transfer process, designing high-performance nonprecious electrocatalysts for the oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) is urgently desired for efficient rechargeable Zn-air batteries (ZABs). Herein, the successful synthesis of porous nitrogen-doped cobalt pyrite yolk-shell nanospheres (N-CoS2 YSSs) is reported. Benefiting from the abundant porosity of the porous yolk-shell structure and unique electronic properties by nitrogen doping, the as-prepared N-CoS2 YSSs possess more exposed active surface, thus giving rise to superior activity for reversible oxygen electrocatalysis and outstanding cycling stability (more than 165 h at 10 mA cm-2) in ZABs, exceeding the commercial Pt/C and RuO2 hybrid catalysts. Moreover, the assembled ZABs, delivering a specific capacity of 640 mAh gZn-1, can be used for practical devices. This work provides a novel tactic to engineer sulfides as high efficiency and promising bifunctional oxygen electrocatalysts for advanced metal-air batteries.

Nitrogen‐Doped Cobalt Pyrite Yolk–Shell Hollow Spheres for Long‐Life Rechargeable Zn–Air Batteries