A decennary update on applications of metal nanoparticles (MNPs) in the synthesis of nitrogen- and oxygen-containing heterocyclic scaffolds

Published on Sep 1, 2020in RSC Advances3.361
· DOI :10.1039/D0RA02272A
Tejas M. Dhameliya8
Estimated H-index: 8
,
Hiren A. Donga1
Estimated H-index: 1
+ 4 AuthorsMahesh T. Chhabria1
Estimated H-index: 1
Sources
Abstract
Heterocycles have been found to be of much importance as several nitrogen- and oxygen-containing heterocycle compounds exist amongst the various USFDA-approved drugs. Because of the advancement of nanotechnology, nanocatalysis has found abundant applications in the synthesis of heterocyclic compounds. Numerous nanoparticles (NPs) have been utilized for several organic transformations, which led us to make dedicated efforts for the complete coverage of applications of metal nanoparticles (MNPs) in the synthesis of heterocyclic scaffolds reported from 2010 to 2019. Our emphasize during the coverage of catalyzed reactions of the various MNPs such as Ag, Au, Co, Cu, Fe, Ni, Pd, Pt, Rh, Ru, Si, Ti, and Zn has not only been on nanoparticles catalyzed synthetic transformations for the synthesis of heterocyclic scaffolds, but also provide an inherent framework for the reader to select a suitable catalytic system of interest for the synthesis of desired heterocyclic scaffold.
References505
Newest
#1T. Krishnaveni (Bharathiar University)H-Index: 1
#2Krishnasamy Lakshmi (Bharathiar University)H-Index: 6
Last. M.V. Kaveri (Bharathiar University)H-Index: 4
view all 4 authors...
A new approach towards the preparation of phase pure NiO nanoparticles via quercetin mediated hydrothermal method is proposed in this work. The performance of quercetin as capping agent is found to be good. The XRD and SEM results confirm that the NiO nanoparticles prepared with quercetin are smaller in size and have refined morphology than that prepared without quercetin. Thermal stability, elemental composition and particle size of prepared nanoparticles have been revealed by TG-DSC, EDAX and ...
Source
#1Li Feng (GDUT: Guangdong University of Technology)H-Index: 1
#2Xuhao Li (GDUT: Guangdong University of Technology)H-Index: 3
Last. Seyed Mohsen Sadeghzadeh (IAU: Islamic Azad University)H-Index: 21
view all 4 authors...
In the present research, a new dendritic fibrous nanosilica (DFNS) based nanocatalyst (DFNS/Dy2Ce2O7) that has high surface zone as well as easy availability of active zones has been properly expanded using an easy approach. DFNS that possess high surface zone is functionalized by amino groups working as the anchors such that the nanoparticles of Dy2Ce2O7 are fine-dispersed onto the DFNS microspheres fibres, without any aggregation. The nanoparticles of Dy2Ce2O7 are produced by a green approach ...
Source
#1Andrew C Flick (Takeda Pharmaceutical Company)H-Index: 2
#2Carolyn A. Leverett (Pfizer)H-Index: 12
Last. Christopher J. O’Donnell (Pfizer)H-Index: 30
view all 10 authors...
New drugs introduced to the market every year represent privileged structures for particular biological targets. These new chemical entities (NCEs) provide insight into molecular recognition while ...
Source
#1Vanna SannaH-Index: 30
#2Mario Sechi (University of Sassari)H-Index: 34
Engineered nanoparticles (NPs) to specifically deliver payload therapeutics to target cells involved in pathophysiological processes seem to offer a powerful strategy to overcome intrinsic limitati...
Source
#2Phuong Hoang Tran (VNUHCM: Vietnam National University, Ho Chi Minh City)H-Index: 16
In this study, we have developed the synthesis of thieno[2,3-b]indole dyes via a multicomponent reaction of cheap and available reagents such as sulfur, acetophenones, and indoles using a magnetic nanoparticle-supported [Urea]4[ZnCl2] deep eutectic solvent as a green catalyst. The synthesis of a series of diversely functionalized thieno[2,3-b]indole has been successfully performed in a one-pot reaction. Among a total of 25 compounds synthesized, there are 21 new compounds with full characterizat...
Source
Source
#1Parvin Ghasemi (Razi University)H-Index: 1
#2Meysam Yarie (Bu-Ali Sina University)H-Index: 18
Last. Morteza Torabi (Bu-Ali Sina University)H-Index: 5
view all 5 authors...
In this exploration, we reported the design and synthesis of a novel ionically tagged magnetic nanoparticles bearing urea linkers, namely, Fe3O4@SiO2@(CH2)3–urea–thiazole sulfonic acid chloride. The structure of the mentioned compound was fully characterized by using several techniques including Fourier transform infrared spectroscopy, energy-dispersive X-ray analysis, elemental mapping analysis, thermogravimetric analysis/differential thermal analysis, scanning electron microscopy, transmission...
Source
#2Pamela MendiorozH-Index: 2
Last. Darío C. Gerbino (UNS: Universidad Nacional del Sur)H-Index: 7
view all 4 authors...
We report an efficient, selective, rapid and eco-friendly protocol for the one-step synthesis of a small xanthone library via an intermolecular catalytic coupling from readily available salicylaldehydes and 1,2-dihaloarenes under ligand-free conditions. To achieve this advantageous direct annulation, we used a novel recoverable palladium nanocatalyst supported on a green biochar under microwave irradiation. Unlike other existing palladium-based approaches, our synthetic strategy showed a greater...
Source
#1Mahdia Hamidinasab (Arak: Arak University)H-Index: 5
#2Mohammad Ali Bodaghifard (Arak: Arak University)H-Index: 10
Last. Akbar Mobinikhaledi (Arak: Arak University)H-Index: 20
view all 3 authors...
Source
#1Yunlong Sun (Guangdong Pharmaceutical University)H-Index: 1
#2Tian Li (Guangdong Pharmaceutical University)H-Index: 1
Source
Cited By6
Newest
Abstract null null Indole, an aza-heterocyclic scaffold, has been found one of the most privileged scaffolds in heterocyclic chemistry and drug discovery. Efforts have been made to provide the complete coverage on the recent development of indole bearing analogues as anti-TB agents reported during 2009 to July 2021 along with their synthetic construction, anti-mycobacterial evaluation, structure-activity relationships, target identification and usages of computer-aided tools in search of suitabl...
Source
Over the past few decades, the use of transition metal nanoparticles (NPs) in catalysis has attracted much attention and their use in C–C bond forming reactions constitutes one of their most important applications. A huge variety of metal NPs, which have showed high catalytic activity for C–C bond forming reactions, have been developed up to now. Many kinds of stabilizers, such as inorganic materials, magnetically recoverable materials, porous materials, organic–inorganic composites, carbon mate...
Source
#1Xiao-Long Ma (Nanjing Tech University)
#2Yu-Han Wang (Nanjing Tech University)
Last. Yi Hu (Nanjing Tech University)
view all 4 authors...
Heterocyclic compounds are representative of a larger class of organic compounds, and worthy of attention for many reasons, chief of which is the participation of heterocyclic scaffolds in the skeleton structure of many drugs. Lipases are enzymes with catalytic versatility, and play a key role in catalyzing the reaction of carbon–carbon bond formation, allowing the production of different compounds. This article reviewed the lipase-catalyzed aldol reaction, Knoevenagel reaction, Michael reaction...
Source
Abstract null null Heterocyclic compounds are among the most prestigious and valuable chemical molecules with diverse and magnificent applications in various sciences. Due to the remarkable and numerous properties of the heterocyclic frameworks, the development of efficient and convenient synthetic methods for the preparation of such outstanding compounds is of great importance. Undoubtedly, catalysis has a conspicuous role in modern chemical synthesis and green chemistry. Therefore, when design...
Source
#1zahra hashemi (Shahrekord University)H-Index: 1
#2Jalal Albadi (Shahrekord University)H-Index: 16
Last. Mehdi Jalali (National Petrochemical Company)H-Index: 4
view all 3 authors...
Nickel oxide nanoparticles supported on melamine as a good alternative to conventional copper catalysts have been prepared and used for the regioselective synthesis of triazole derivatives in water. This catalyst can be reused several times without any significant decrease in the catalytic activity. The nanocatalyst was characterized by Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), field emission scanning electron microscopy (FESEM), energy-dispersive spectro...
Source
#1Fatemeh Majidi Arlan (Academic Center for Education, Culture and Research)H-Index: 3
#2Ahmad Poursattar Marjani (Urmia University)H-Index: 10
Last. Jabbar Khalafy (Urmia University)H-Index: 14
view all 4 authors...
The synthesis of heterocyclic compounds containing a bioactive core including the pyridine molecular framework with diverse pharmaceutical and biological activities is noteworthy. Recently chemists have created novel active pharmacophores via MCRs in the presence of nanocatalysts. The application of various types of nanoparticles as catalysts has been studied in the formation of polyfunctionalized pyridines via multicomponent reactions, and is the subject of this review, which concentrates on th...
Source
#1Mitat Akkoç (Turgut Özal University)H-Index: 5
#2Nesrin Buğday (İnönü University)H-Index: 6
Last. İsmail Özdemir (İnönü University)H-Index: 37
view all 6 authors...
Abstract A new type magnetic nano Fe3O4@SiO2@NHC@Pd-MNPs heterogeneous catalyst was fabricated and characterized by Fourier Transform Infrared (FTIR) spectroscopy, Transmission Electron Microscopy (TEM), X-Ray Diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), Energy Disperse X-ray analysis (EDX), Thermogravimetric Analysis (TGA), Differential Thermal Analysis (DTA), and Scanning Electron Microscopy (SEM). The loading amount of Palladium (Pd) to magnetic nano Fe3O4@SiO2@NHC@Pd-MNPs was m...
Source
#1Mitat Akkoç (Turgut Özal University)H-Index: 5
#2Nesrin Buğday (İnönü University)H-Index: 6
Last. Sedat Yaşar (İnönü University)H-Index: 18
view all 4 authors...
Source
#1Serve Sorkhabi (University of Kurdistan)H-Index: 2
#2Mohammad Ghadermazi (University of Kurdistan)H-Index: 24
Last. Roya Mozafari (University of Kurdistan)H-Index: 4
view all 3 authors...
Source
This website uses cookies.
We use cookies to improve your online experience. By continuing to use our website we assume you agree to the placement of these cookies.
To learn more, you can find in our Privacy Policy.