Copper(I)-catalyzed diastereo- and enantio-selective construction of optically pure exocyclic allenes

Volume: 11, Issue: 1
Published: Aug 27, 2020
Abstract
Among about 150 identified allenic natural products, the exocyclic allenes constitute a major subclass. Substantial efforts are devoted to the construction of axially chiral allenes, however, the strategies to prepare chiral exocyclic allenes are still rare. Herein, we show an efficient strategy for the asymmetric synthesis of chiral exocyclic allenes with the simultaneous control of axial and central chirality through copper(I)-catalyzed...
Paper Details
Title
Copper(I)-catalyzed diastereo- and enantio-selective construction of optically pure exocyclic allenes
Published Date
Aug 27, 2020
Volume
11
Issue
1
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