One-pot two-step chemoenzymatic deracemization of allylic alcohols using laccases and alcohol dehydrogenases

Volume: 493, Pages: 111087 - 111087
Published: Sep 1, 2020
Abstract
A series of enantioenriched (hetero)aromatic secondary allylic alcohols has been synthesized through deracemization of the corresponding racemic mixtures combining a non-selective chemoenzymatic oxidation (laccase from Trametes versicolor and oxy-radical TEMPO) and a stereoselective biocatalyzed reduction (lyophilized cells of E. coli overexpressing an alcohol dehydrogenase, ADH). Both steps were performed in aqueous medium under very mild...
Paper Details
Title
One-pot two-step chemoenzymatic deracemization of allylic alcohols using laccases and alcohol dehydrogenases
Published Date
Sep 1, 2020
Volume
493
Pages
111087 - 111087
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