Effects of Aspect Ratio Heterogeneity of an Assembly of Gold Nanorod on Localized Surface Plasmon Resonance

We examine the effects of aspect ratio (AR) heterogeneity of an assembly of gold nanorods (GNRs) in a colloid on the total cross-section for its light scattering via localized surface plasmons at visible wavelengths. We observe the extraordinary broadening of the extinction spectrum of light through an assembly of GNRs, a colloidal mixture of those having two different ARs. The interparticle distance estimated as ∼1.2–1.3 μm, being greater than...