Synthesis and properties of σ‐π conjugated porous polymers obtained with Mizoroki–Heck reaction of tetra vinyl cyclic siloxane with dibromo fluorene

Volume: 58, Issue: 17, Pages: 2301 - 2309
Published: Jun 29, 2020
Abstract
σ‐π Conjugated porous polymers were synthesized by the Mizoroki–Heck reaction of cyclic siloxane with vinyl groups, 1,3,5,7‐tetravinyltetramethylcyclotetrasiloxane (TVMCTS), and 2,7‐dibromo‐9,9‐dialkylfluorene (RFl) compounds, using a Pd catalyst in N , N ‐dimethylformamide (DMF) at 100°C. The reactions of TVMCTS in combination with 2,7‐dibromo‐9,9‐dihexylfluorene (HFl), 2,7‐dibromo‐9,9‐dioctylfluorene (OFl), and...
Paper Details
Title
Synthesis and properties of σ‐π conjugated porous polymers obtained with Mizoroki–Heck reaction of tetra vinyl cyclic siloxane with dibromo fluorene
Published Date
Jun 29, 2020
Volume
58
Issue
17
Pages
2301 - 2309
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