C(sp3)-H functionalizations of light hydrocarbons using decatungstate photocatalysis in flow.

Science56.90
Volume: 369, Issue: 6499, Pages: 92 - 96
Published: Jul 3, 2020
Abstract
Direct activation of gaseous hydrocarbons remains a major challenge for the chemistry community. Because of the intrinsic inertness of these compounds, harsh reaction conditions are typically required to enable C(sp3)–H bond cleavage, barring potential applications in synthetic organic chemistry. Here, we report a general and mild strategy to activate C(sp3)–H bonds in methane, ethane, propane, and isobutane through hydrogen atom transfer using...
Paper Details
Title
C(sp3)-H functionalizations of light hydrocarbons using decatungstate photocatalysis in flow.
Published Date
Jul 3, 2020
Journal
Volume
369
Issue
6499
Pages
92 - 96
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