Enzymatic Primary Amination of Benzylic and Allylic C(sp3)–H Bonds
Volume: 142, Issue: 23, Pages: 10279 - 10283
Published: May 25, 2020
Abstract
Aliphatic primary amines are prevalent in natural products, pharmaceuticals, and functional materials. While a plethora of processes are reported for their synthesis, methods that directly install a free amine group into C(sp3)–H bonds remain unprecedented. Here, we report a set of new-to-nature enzymes that catalyze the direct primary amination of C(sp3)–H bonds with excellent chemo-, regio-, and enantioselectivity, using a readily available...
Paper Details
Title
Enzymatic Primary Amination of Benzylic and Allylic C(sp3)–H Bonds
Published Date
May 25, 2020
Volume
142
Issue
23
Pages
10279 - 10283
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