Chemoselective oxidative generation of ortho -quinone methides and tandem transformations

Volume: 12, Issue: 4, Pages: 353 - 362
Published: Mar 23, 2020
Abstract
ortho-Quinone methides are useful transient synthetic intermediates in organic synthesis. These species are most often generated in situ by the acid- or base-mediated transformation of phenols that have been pre-functionalized at a benzylic position, or by biomimetic oxidation of the corresponding ortho-alkylphenols with metal oxidants or transition-metal complexes. Here we describe a method for the transition-metal-free oxidative generation of...
Paper Details
Title
Chemoselective oxidative generation of ortho -quinone methides and tandem transformations
Published Date
Mar 23, 2020
Volume
12
Issue
4
Pages
353 - 362
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