Ruthenium-Catalyzed Tandem Carbene/Alkyne Metathesis/N–H Insertion: Synthesis of Benzofused Six-Membered Azaheterocycles
Abstract
The Cp*RuCl-based catalyst enables expedient access to a variety of benzofused six-membered azaheterocycles from unprotected o-alkynylanilines and trimethylsilyldiazomethane through an unprecedent tandem carbene/alkyne metathesis/N-H insertion reaction. The transformation takes place under mild reaction conditions (room temperature, <15 min) and with excellent functional group tolerance. The synthetic utility of the final products and a...
Paper Details
Title
Ruthenium-Catalyzed Tandem Carbene/Alkyne Metathesis/N–H Insertion: Synthesis of Benzofused Six-Membered Azaheterocycles
Published Date
Mar 16, 2020
Journal
Volume
22
Issue
7
Pages
2621 - 2625
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